1/23/2024 0 Comments Ecto cooler loki![]() ![]() It’s always the game within the game with you guys - which I respect.Īgain, I cannot get enough of this conversation. Of course, that just makes him more likely to be a Loki. Mobius: I don’t know – he could be lying. I mean, who’s to say he’s even a Loki variant? Mobius: You know the TVA has arrested a lot of Loki’s but I don’t remember an Alligator. Now that is a central theme which can be argued one way or another.įor our purposes here, there is a lighthearted introspection into who a Loki is when Old Loki and Mobius have a fireside chat about the true identity of Alligator Loki. What is a Loki? Can Loki be good? Who is a Loki? Or, in the instance of “Journey Into Mystery”, Lokis, most of all, want connection. It is a Mary & Blake Media commandment that theme must be a question, or, an argument. Those are nothing more than abstract notions. I will admit though, while all the aforementioned traits are certainly an asset to the penultimate episode of Loki, there is another, far more, important facet which really cements my sheer joy and that is the exquisite execution of theme and anti-theme.Īs you all know, theme is NOT a word, or phrase like: “brotherhood”, or “love”. Featuring incredible effects, multiple versions of Loki, well shot action scenes, and just the right amount of absurdity (I’m looking at you Frog Thor), I think this might be my favorite episode of any MCU show yet. Setting aside my love of all things reptile integrity, this is the EXACT kind of episode I was looking for when I first heard Loki was to become a series on Disney+ (#NotASponsor). Grant and Owen Wilson debating the true identity of an alligator, you know you’re in for a fantastic ride. ![]() Let’s just make one thing very clear at the beginning of this article, any time, and I mean ANY TIME, you have an episode of television which features Richard E. anti-theme” mirror for our main character as it builds brilliant momentum heading into the season finale. Loki episode 1.05 “Journey Into Mystery” is a straight up bananaland episode of television which serves as a perfect “theme vs. Ecto Cooler buds have tight neon green grape-shaped nugs with thin orange hairs and a coating of tiny golden crystal trichomes.UNLOCK BONUS EPISODES, PREMIUM PODCASTS & MORE Join The #NerdClan The aroma is very citrusy and lemony with a gassy overtone that's almost like burning fuel. Ecto Cooler has a super sweet citrusy pine flavor with just a touch of sharp chemicals on the exhale. Thanks to these effects, Ecto Cooler is often chosen to treat a wide variety of conditions including chronic stress, mood swings, insomnia, chronic pain, and chronic fatigue. You'll feel an influx of creative ideas and focus, making this bud perfect for when you need to get down to business. The Ecto Cooler high has a lifted energizing onset that fills your mind with bright thoughts and pulls you into a giddy state of euphoria. With its super high 15-20% average THC level and lifted effects, this high-powered bud will eradicate any haunting aches and pains with ease. This bud gets is name as a throwback to the original Ghostbusters and brings on a classic high that any user will love. Sativa Dominant Hybrid - 70% Sativa / 30% Indica THC:Įcto Cooler is a sativa dominant hybrid strain created as a cross of the delicious California Orange X Gorilla Biscuit strains. ![]()
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![]() ![]() ![]() This versatile organizer works for any bathroom as a solid over-the-toilet storage solution. Here, the best over-the-toilet storage units, so your bathroom can stay totally organized. To see how all the options on the market stacked up, we researched dozens of options, judging each one on ease of assembly, capacity, and sturdiness. “Using an étagère can add functionality to your bathroom where it didn't exist previously and allows you to keep frequently used items, like toilet paper and clean towels, easily accessible," she explains. “ can have open shelving, drawers, or even cabinets.” The final result makes items easy to store, access, and style. Saltman explains that the beauty of these types of storage units is that they come in several styles, meaning there’s a fit for every design, need, and budget. Simplified, to find out more about using over-the-toilet shelving and storage units (known as an étagère) to maximize all the vertical wall space in your home, while adding extra storage. ![]() We checked in with Lauren Saltman, professional organizer and owner of Living. No matter how cramped or large your bathroom is, there are tons of organizational solutions to make the space feel clutter-free and functional, though-right down to the last backup roll of toilet paper or container of cotton balls. The Spruce Home Improvement Review Boardīathroom storage is essential, but can often be extremely scarce. ![]() 1/23/2024 0 Comments Little hoppa 3 in 1![]() ![]() Our deposits had been paid, (from the sales of our house EEEEK), money had been spent on websites, marketing, imagery, videos, samples, we were ALL IN, in a VERY BIG way! ![]() Our factory closed for 3 months, and we had no idea when or even if they would ever re-open. We sold the London home that my husband and I had spent 5 year painstakingly renovating, to fund the deposit of our first Little Hoppa order (yes he is still married to me…just about LOL).Īnd then just as we were about to commence manufacturing of our first order…Ĭhapter 5 - The course never runs smoothly The 2 years that followed were fraught with challenge! It took 18 months of back and forth with a team of engineers, multiple manufacturers, countless samples and trips around the globe before we finally got it right. By then, my side-hustle styling and content creation business had taken off, and was just about keeping me afloat whilst I invested into my big idea! It was September 2018, I decided to hand in my notice from Barclays where I was VP in HR, so I could focus on launching Little Hoppa and growing my own product-based business. I finally plucked up the courage to do something about this thing, if no one else was going to do it, why not me? It was 20 months after ‘The list’ that my second baby, Reggie, arrived.Īnd once again, whilst feeding my new baby, I looked at the market to see if anyone had addressed the gap that that had been there 20 months ago, and to my surprise, they hadn’t. I searched high and low for a wooden baby bouncer, because the one we had, (which all the Mums I knew had bought and loathed) was just such an eye-sore, and not particularly well designed either! I was surprised to discover that nothing existed.Ĭhapter 3 – It started with a list on a scrap of paperĪnd so, right there, whilst feeding my baby on the sofa, I wrote a list of all the things as a Mum with a keen interest in design, and a desire to invest in more natural, planet friendly products, I could not find! It was a pretty long list and one that I am still adding to today.Ĭhapter 4 – Turning the big idea onto a reality …. The whole idea of toxic plastics going into our babies mouths, and then going to land fill and washing up on beaches, it just didn’t sit well with me!Īnd so.I started doing what all budding entrepreneurs do, I hit google search HARD! Many late-night feeds were spent trawling the internet. I had wanted to try and avoid plastic where I could with my babies, not just because I hate the look of plastic, but also because it is just SO bad for the planet and our health too. I could not really understand how the baby industry, at least in the UK, had so little to offer parents looking for alternatives to plastic, and baby products with style. There was stuff EVERYWHERE, products I had bought largely out of a sheer lack of choice or alternatives. I no longer recognised myself, or my home! Every corner was covered in baby tat, large bulky items that were rarely used and that my baby seemed to grow out of as quickly as we were buying them. ![]() I was loving being a Mum, but I looked around at the home I had so passionately and painstakingly designed, and it had been taken over. I was sat in my living room, tired, hungry, and quite possibly still in my PJ’s. It was about 6 months into my maternity leave, from a then 12-year career in Recruitment & HR, that I had what I can only really describe as one of life's significant moments. With his almond eyes and his Wella-Shock-Waves hair, it is fair to say that he’s been stealing hearts since day dot. Here’s Teddy, the very reason by Sofie exists! the baby the nurses affectionately named ‘The Disney Prince’. ![]() 1/23/2024 0 Comments Mr ze batman and robin frrrze![]() Freeze, you could tell it was meant for somebody who would deliver it in a Shakespearean fashion. Freeze’s lines were written for someone more like Stewart than Schwarzenegger: “All the dialogue was for Mr. Storyboard artist Tim Burgard remembers working from an earlier script in which Mr. (Here’s something extra for all of you Batman & Robin conspiracy theorists out there. “I had met with Arnold several times, because he was always interested in working together.” One of the most enduring myths about Batman & Robin is that Patrick Stewart was up for Mr. “I went to the Valley, where George lived with his pig and his great friends, and we said, ‘Let’s do it,'” recalls Schumacher. exec Bob Daly suggested a handsome rising star from the TV world to step in. He wanted to do Island of Doctor Moreaubecause Marlon Brando was going to be in it. “ Batman Forever, when we were on the world tour, it just really went to his head,” says Schumacher of Kilmer’s exit, before stopping himself. Those who worked on Batman Forever weren’t particularly surprised that Kilmer opted not to return, as he and Schumacher didn’t quite get along. Some of the tidbits you’ll find below include a look at Schwarzenegger’s larger-than-life presence on set (complete with Cuban cigars hand-delivered by Jon Bon Jovi), the double standard Alicia Silverstone faced after accepting the role (including an insensitive drawing that circulated during preproduction) and a look at some of Batman & Robin‘s most enduring rumors (including the one Star Trek fans will be crushed to learn isn’t true).Īrnold signed on for a cool $25 million - and no, Patrick Stewart was not up for Mr. At the same time, there’s plenty of good in Batman & Robin, and that’s covered here too. Competing corporate interests helped push Batman & Robin to becoming a very, very expensive toy commercial rather than a movie in its own right. What’s clear: the film was a victim of franchise-mania. It’s hard to pinpoint why the movie didn’t shape up as hoped. To find out what did go wrong, Heat Vision caught up with Schumacher and eight other people who labored over the film. ![]() 1/23/2024 0 Comments Lumenrt materials![]() ![]() Component Array: This plugin though named like the collection in AutoCAD should not be flawed as such because component array is still limited in comparison to that. This is one of the best SketchUp plugins for making 3D object with softer edges.ħ. Then, click the check mark to preview the result and strike enter to exit the plugin. You have to pick the corner(s), which the user wants to be round, sharp or bevel then click the corresponding tool and modify the palette according to your preferred outcome. Round corner is made of 3 tools, which are for making corners round, sharp and bevel. Round Corner: Just like all the plugins made by fredo6, the sketchup enthusiasts require to download first the latest version of libfredo6 to be able to use all his other plugins. This will absolutely make your SketchUp file less in size thus adding speed in your drawing and rendering.Ħ. This is different from using Model Info because you have the option of what to purge on and also have a log or report made on what was removed. This important plugin helps you eliminate idle and unutilized components, layers, materials and styles. Purge All: Purge all plugin for sketchupPurge, purge, purge as they always says. ![]() This plugin is used to mirror groups, components or raw geometry thus making it easier to manufacture multiple objects in a file without making them again from scratch.ĥ. ![]() You would then be asked to decide to delete or keep the original object. This is complete by selecting the object to be mirrored and then picking points to describe a line, points or a surface. Mirror: At first it was discovered by Frank Wiesner and rewritten by TIG from version 3.1 up to the newest version to date. ![]() Furthermore, the user can import or export roof styles.Ĥ. Editing the slope, eaves, fascia, hip, and rafter settings can adapt the roof style. Additionally, user can create your own style through having your own roof, eaves, hip, and rafter parameters. The choices of roofs include gambrel, mansard, ranch, craftsman, Elizabethan, new roof style, plantation, prarie, santa barbara, ski lodge and trellis. Once the face is selected, you only have to decide the type of roof you want. Instant Roof: This is used for creation of a roof quickly. 1001 bit tools will build life easier for SketchUp users.ģ. What is preferable in this plugin is the formation of a hip roof, walls, opening frames, stairs and extruding profiles along a chosen path without twisting even if the path is sloping. This plugin is a “one stop shop tools” for the cause that it has wide uses from drawing a line on a surface, making window frame, to setting up a hip roof. 1001 bit Tools: This contains 39 different tools which are supportive for a budding SketchUp user. This would permit the designer a chance to adapt how tall and thick the greenery will be to his/her mental fulfillment.Ī trouble-free, speedy and easy to use and once the surface have selected, the user can utilized the plugin, imputing the coveted setting and viola. This will deliver a blade of grass and greenery in general. This is used in making “fur” on a created face by inputting certain type and figures in the fur settings. In fact the cleverness of SketchUp users are remarkable. Fur Plugin: This plugin is utilized by different SketchUp enthusiasts in making grass, greenery, carpet and in various other creative lines. This is an excerpt of the article published by with reference to Tak2hata, Goh Chun Hee, Chuck Vali, TIG, Fredo6, sdmitch, Fredo6 and Chaos Groupġ. Some of the best are Instant Roof, Purge All, Fur, 1001 Bit Tools and Curviloft SketckUp plugins. Most of them are free of charge and can be redrafted by anybody inspired enough to fill the gap of increasing easy to use plugin.Īll of these ten plugins are precious to a SketchUp user and enthusiasts in gaining photo realistic 3D model. Plugins or scripts are broadly added to SketchUp for strengthening the 3D experience capability. SketchUp is a 3D modelling program possessed by Trimble Navigation and utilized by designers in engineering and architecture. ![]() 1/23/2024 0 Comments Football manager 2016 training![]() Your coaching staff will also have a big impact on your players’ development. Try to convince the board to upgrade them if necessary. The rating of your Youth Facilities will affect the overall training quality of the lowest age group youth team at your club, while Training Facilities will influence the overall training quality of your Senior, Reserve and other youth squads (if applicable). Tip: You can use the search filter: Conditions – General – Personality when trying to find a suitable tutor in Football Manager 2016. Remember that a youngster can only be tutored by older players who have a more important Squad Status assigned (and better Reputation). Tutoring won't just determine a personality change, but the tutee will also inherit the tutor’s Determination attribute, so have that in mind before starting assignments. ![]() You can fix that by asking older players with better personalities to tutor them, using the second option ‘mentor off the pitch’. But don’t worry if they haven’t got the right mentality when you sign them. You should aim for the best possible personality for your youngsters. You can fix that by asking older players with better personalities to tutor them The Bad: Slack, Casual, Temperamental, Unambitious, Easily Discouraged, Low Determination, Spineless and Low Self-Belief.Īnd The Neutral: Jovial, Light Hearted, Devoted, Very Loyal, Loyal, Fairly Loyal, Honest, Sporting, Unsporting, Realist and Balanced.ĭon’t worry if they haven’t got the right mentality when you sign them. The Good: Model Citizen, Perfectionist, Resolute, Model Professional, Professional, Fairly Professional, Spirited, Very Ambitious, Fairly Ambitious, Ambitious, Driven, Determined, Fairly Determined, Charismatic Leader, Born Leader, Leader, Iron Willed and Resilient. ![]() 1/23/2024 0 Comments Newpipe moodd apk![]() Now if how can I watch YouTube content in this NewPipe APK, so basally it’s an alternative APK of YouTube which also allow all the YouTube content with some extra features free which has only you will get with the premium membership of YouTube. Also, this NewPipe APK is so lighter than original YouTube, so it’s also taking less data to watch any videos. If you are frustrated with YouTube ads while watching YouTube videos then you can install the NewPipe APK because this application offers their users completely ads free performance. ⇒Recommend: NewPipe APK (Official) Conclusion Basically, using the NewPipe APK, there was no sign required. And you can do all things without any sign in. But this NewPipe APK never ask for sign in to do all the things you just have to install the application. So if you want to watch YouTube videos without having any ads then you have to install the NewPipe APK No Sign-In RequiredĪs we all know that while first time opening YouTube there was required to sign in, otherwise you can’t do any download videos. Because this APK was to offer all the content from YouTube without any ads. The main reason people hate about YouTube is it’s showing endless ads while watching videos, Now if you are also one of them who also don’t like to watch single ads then you can download this NewPipe APK. So now just download the NewPipe APK, because this application allow you to download any videos in your device, even you can download them as an audio. ![]() Many of YouTube content many people are want to download into their mobile, but the thing is YouTube never allow you to download their content in your device, but you can download them into your YouTube account, And you can watch all but you can’t share them. Otherwise, if you are trying to watch those all blocked videos then you can’t see them, there was just showing that this content is age-restricted. But now don’t worry, NewPipe APK will be help you to watch all those content from YouTube that all are age-restricted material. Watch Blocked ContentĪs we all know that YouTube has lots of age-restricted material videos, and you can’t able to see those videos. And the main thing is you can play videos in the background, so now you don’t have to on your mobile’s screen always. If you are love to listen musics and while listening musics on YouTube you have to on the phone screen, then just stop using the original application and start to use this NewPipe APK because this APK support all the YouTube videos, and you can watch or listen those all YouTube content. So if YouTube is too heavy for you, then you can install the NewPipe and enjoy all YouTube content using fewer data. Using the APK you can even change the theme like dark and others. Now, this NewPipe was offered by an unknown developer. Many people are don’t know this application, but it’s a pretty popular on the internet. Let’s explore the NewPipe APK here, Basically it’s an alternative application that allow you to watch all YouTube content without having any ads also many others features that YouTube allow only premium membership users. ⇒Also Read: Youtube Vanced (Premium, Ads free) Introduction So if you want to watch YouTube videos without ads even free then you have to install this NewPipe APK from here, also uses fewer data compared to YouTube. But this NewPipe APK gives you the same ads free performance without a single penny. ![]() Now if you want to watch YouTube videos without having any ads then you have to take a premium unlock which is you can get with money. ![]() Using the original YouTube, there are lots of ads while watching anything and no one love to watch ads while watching any entertain content. So now if you want to use YouTube without having any ads then you have to install this NewPipe MOD APK. The best and finest thing of this NewPipe APK is it’s totally ads free application that you can use in android device. Now that application is NewPipe APK here you can find the same interface, and it’s an alternative version of YouTube which is easier to use. ![]() Also, the application I am going to explore which also so lighter than original YouTube, so you can even save your space and data too. NewPipe MOD APK: Hey you are an android user, and you are frustrated with using the YouTube APK because of their endless annoying ads, Then today in this post I am sharing a really helpful application for you. Introduction Play Videos In Background Watch Blocked Content Download Any Content Watch Videos Ads Free No Sign-In Required Conclusion Download and Install Guide Related FAQ’s ![]() 1/23/2024 0 Comments Polske radia online![]() ![]() The winners of the four awards above can run for the Academy Awards, as the Short Films Competition at the Warsaw International Film Festival is on the Oscars eligibility lists at 7. Special Mention Live Action: HEDGEHOG'S DILEMMA / MIASTO JEŻY, dir. Best Documentary Short: EMPTY HOURS / LES HEURES CREUSES, dir. Best Live Action Short: PICTURE DAY, dir. SHORT FILMS COMPETITION Jury members Masha Kondakova (Ukraine), Piotr Jasiński (Poland), Oliver Adam Kusio (Poland/Germany) gave the following awards:Ħ.1. The Jury justification: "To brave filmmakers for evocative, cinematic, visually poetic film language and tender human view on life of civilians and especially children in the time of war."Ħ. The Best Documentary Feature Award was won by: PHOTOPHOBIA by Pavol Pekarcik & Ivan Ostrochovsky (Slovakia/Czechia/ Ukraine). DOCUMENTARY COMPETITION Jury members Aniela Astrid Gabryel (Poland), Oleg Shcherbyna (Ukraine), Marko Škop (Slovakia) gave the following awards: And for lifting young talents to a level of mature partners in crime."ĥ. The Jury justification: "For the filmmaker’s exquisite craft to harness the endearing world of adventure, friendship, and devil-may-care charm into a reminder of what a film can do. ![]() FREE SPIRIT COMPETITION Jury members Samppa Batal (Finland), Olga Chajdas (Poland), Maciej Kawalski (Poland) gave the Free Spirit Award to: RIDDLE OF FIRE by Weston Razooli (USA). Special Mention went to: DIAGNOSIS: DISSENT / БОЖЕВІЛЬНІ by Denys Tarasov (Ukraine)Ĥ. COMPETITION 1-2 Jury members Feliks Falk (Poland), Linda Olte (Latvia), Ran Li (China) decided that the Competition 1-2 Winner is WITHOUT AIR / ELFOGY A LEVEGŐ by Katalin Moldovai (Hungary) ![]() Jury justification: "For an empathetic story about the fate of a donkey in the human world, which teaches us respect for other beings, our roommates on earth".ģ. Jury justification: "For the moving image of man's cruelty towards others, which reveals various forms of violence and leads to racism, nationalism and genocide." Felipe Gálvez (Chile/ Argentina/UK/Taiwan/France/Denmark/Sweden/Germany) CREME DE LA CREME COMPETITION Jury members Irena Strzałkowska, Natalia Koryncka-Gruz, Grzegorz Pacek - all from Poland, gave the following awards:Ĭrème de la Crème Award: THE SETTLERS / LOS COLONOS, dir. The Jury justification: "for the emotional and poetic image of the inner world of two teenagers in the contemporary Eastern European reality".Ģ. Zdeněk Jiráský (Czechia/ Romania/Slovakia). Special Jury Award went to I DON'T LOVE YOU ANYMORE / UŽ TĚ NEMÁM RÁD, dir. The Jury justification: "for the courage to delve in an extreme yet beautiful way into a much explored genre and successfully finding a way to portray important, vulnerable, and relevant aspects of the human condition".ġ.3. Award for the Best Director went to THE LAST MEN / LES DERNIERS HOMMES, dir. ![]() The Jury justification: "touching and delicate, universal and personal cinematographic journey into the depths of human soul".ġ.2. The Warsaw Grand Prix includes 100,000 zlotys cash award, funded by the Mayor of Warsaw. Jorge Hernandez Aldana (Venezuela/Mexico) Warsaw Grand Prix went to THE SHADOW OF CATIRE / LA SOMBRA DEL CATIRE, dir. INTERNATIONAL COMPETITION Jury members Dorota Kędzierzawska (Poland), Nadejda Koseva (Bulgaria), Yurii Andrukhovych (Ukraine), Alejandro Torres Kennedy (Mexico)ł gave the following awards:ġ.1. On The Search For Love / Starsza pani szuka, dir. Don't Mess with Gienek / Nie z Gienkiem te numery, dir. Basia Three Short Stories / Trzy opowiadania o Basi, dir. Scream of My Blood: A Gogol Bordello Story, dir. The Crossing: Consequences of the Truth, dir. Paweł Hejbudzki, Poland/Mexico/Netherlandsģ. Ani Choying Drolma: Mission Impossible, dir. Mohamed Kordofani, Sudan/Egypt/France/Germany/Saudi Arabia/Swedenģ. Sławomir Fabicki, Poland/Switzerland/GermanyĢ. Here are the films, which were liked the most by the audience of the 39th Warsaw International Film Festival, which came to an end yesterday.ġ. ![]() 1/23/2024 0 Comments Fontself maker for illustrator![]() Once you’re happy with your font, click the Export button to save it as a regular Opentype (OTF) font that you can then distribute as you wish. Click the Install button to try out the font directly in Illustrator. You can now experiment with the font as much as you want, and modify those glyphs that aren’t working as you would like them to. To see how the font works in practice, click Fontself’s Install button and it will be installed directly into Illustrator, with no further action required on your part. Type in the Preview pane to see your font in action. This makes it easy to see at a glance whether all the glyphs work together. Once your glyphs are all in place, you can type some sample text into Fontself’s preview pane to see it set in the font you’ve just created. Drag a whole alphabet and the letters are identified en masse. You can drag numbers into the Fontself panel in the same way. You’ll see the whole alphabet in the Preview pane as soon as you drag the glyphs into place. When you drag an entire alphabet, there’s no need to assign keystrokes to the individual characters – this is done automatically for you (assuming the letters are all in the correct order). You can select all the glyphs in an alphabet and drag them in a single operation. There are specific locations for lowercase and uppercase glyphs, and for numbers. To create an alphabet, select all the upper or lower case characters and drag them, along with the baseline, into the Fontself window. You can drag a whole string of glyphs at once. Here, all the punctuation is dragged into the panel in one go, and it’s then a simple matter to type the keyboard triggers for hyphens, dashes, brackets and so on. You don’t need to drag just a single glyph at a time – you can drag a whole selection if you like. Dragging a glyph with its baseline positions it correctly. You can see here how the inverted commas are now placed floating at the top of the character space. Now, you can drag a glyph together with its baseline into the Fontself panel, and it will be correctly positioned. Drag guides to the baselines to mark the vertical position of the characters. This is most accurately done by first switching to Outline view, so you can see precisely where to position the guides. The solution is to drag guides into place from Illustrator’s rulers, aligning them with the baseline of the glyphs. All glyphs are placed on the baseline, whether you want them there or not. When these are dragged into the panel, the default behavior is to place them on the baseline as well. This method works fine for fonts that sit on the baseline, but there are problems for floating glyphs such as inverted commas. Type the key you want to use to trigger the glyph. Once the glyph is in place, you can type its keyboard equivalent so that it can be triggered with that keystroke when the font is complete. Glyphs can be dragged one at a time into the Fontself panel. Here, we’re dragging the question mark symbol by itself, and dropping it onto the appropriate area of the panel. To turn the shapes into a font, you can select individual letters and drag them into the Fontself panel. Use small values in the Roughen filter to preserve legibility. ![]() By using very small Size and Detail settings, it’s possible to keep the font legible while making a clear difference. ![]() You can use any of Illustrator’s distortion filters to corrode the text here, we’re using the Roughen filter to randomize the outlines. Convert the text to outline mode using Type > Create Outlines. Turning the characters to Outline allows us to modify the paths directly. To begin, we’ll type out a character set, including both upper and lower case, as well as numbers and any other punctuation marks and symbols we’ll need. In this article, we’ll look at the process of creating a new font based on an old classic: we’ll use Illustrator’s filters to corrode Helvetica and then build a font I call “Crudvetica” from the resulting glyphs. Fontself Maker works with Illustrator CC 2015. Because it’s a plug-in rather than a separate application, you can use the Illustrator tools you’re familiar with to create personalized fonts with ease. Fontself Maker, the result of a 2015 Kickstarter campaign, is an Illustrator plug-in that allows you to create custom fonts directly from within the program. ![]() 1/23/2024 0 Comments Molecular geometry table of2![]() ![]() Let us look at the electronic configuration of oxygen and fluorine in their ground states.Īfter forming bonds with halogen F and attaining octet configuration, the electronic structure of O looks like this: If we take into account the combination of wave functions of several atomic orbitals, we come across the process of hybridization.įor example, the wave functions of the s and a 2px orbitals give rise to sp hybridization which usually results in a linear geometry. We have s,p,d,f atomic orbitals ( AOs ).Įlectrons can be explained via their wave functions in quantum mechanics. An orbital, on the other hand, is defined to be the probability of the presence of an electron in any given regional space.Ītomic orbitals are of several shapes like spherical, dumb-bell, clover-leaf, or doughnut to name a few of the complex varieties. In chemistry, an orbit is a fixed path around the nucleus in which electrons tend to move or revolve. The bond angle is around 103 degrees (due to the repulsion of the lone pair). According to the above chart, we have a bent molecule structure. The VSEPR notation for the OF2 molecule is AX2E2. of lone pairs of electrons of the central atom, ‘X = 2. of surrounding atoms, ‘n’ = 2 ( Fluorine )Į: no. Let us look at this VSEPR chart showing AXN notations:Īccording to AXnEx notation of VSEPR theory, The VSEPR model tends to reduce or minimize the repulsive forces and balance the stability of any given molecule, in this case, OF2. ![]() Like charged electrons create a negatively charged cloud surrounding the atomic nuclei and repulsion is created. Our next step is to use Valence Shell Electron Pair Repulsion Theory (VSEPR) to find the exact molecular geometry along with the bond angles. Via Lewis Structure, we have realized the type of bond formed and the number of lone or unbonded pairs of valence electrons present in an OF2 molecule. Now, we are going to decipher the 3D molecular shape. We have already found the 2D Lewis Structure diagram of the Oxygen Difluoride molecule. Here, oxygen forms a single bond with each of the fluorine atoms (O-F). Since the elements are present in their least possible formal charge values, we have achieved our suitable Lewis Structure configuration. The same goes for the central oxygen atom.īefore we proceed to confirm any sketch to be the perfect Lewis Structure for a given molecule or ionic structure, we need to check the formal charge values.įor Oxygen: Formal Charge = 6 – 0.5*4 – 4 = 6 – 2 – 4 = 0.įor each Fluorine atom: Formal Charge = 7 – 0.5*2 – 6 = 7 – 1 -6 = 0. Here, if we look at the octet rule, both the fluorine atoms have achieved a valency of eight. This is known as octet fulfillment since the elements want to achieve eight electrons in their valence shells.įor example, Carbon tends to attain a Neon configuration.Įxception: Hydrogen tends to achieve Helium configuration, hence only two electrons in the outer shell. The main group elements ( group 1 to group 17 ) of the periodic table have a tendency to attain the octet configuration of the noble gas elements present in group 18 of the same period.
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